The difference between More often than not and Most of the time
When used as adverbs, more often than not means usually, whereas most of the time means on most occasions.
check bellow for the other definitions of More often than not and Most of the time
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More often than not as an adverb:
Usually; more than half the time; more likely to be the case than not to be the case.
Examples:
"'More often than not, tomato seeds will sprout even if they are a couple of years old."
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Most of the time as an adverb:
on most occasions; usually