The difference between Backfriend and Unfriend
When used as nouns, backfriend means a false friend, whereas unfriend means one who is not a friend.
Unfriend is also verb with the meaning: to sever as friends.
check bellow for the other definitions of Backfriend and Unfriend
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Backfriend as a noun (UK, dialectal, obsolete):
A false friend; a secret enemy.
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Backfriend as a noun (UK, dialectal):
A friend at one's back; a backer; one who does his best for another; a supporter.
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Backfriend as a noun (UK, dialectal):
A hangnail.
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Unfriend as a noun:
One who is not a friend; an enemy.
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Unfriend as a verb (rare):
To sever as friends.
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Unfriend as a verb (Internet):
To defriend; to remove from one's friends list (e.g. on a social networking website).